INS study of multifunctional zeolites for catalytic conversion of methanol to propene

DOI

Efficient synthesis of light olefins from renewable resources remains a major challenge. We request 6 days on MAPS to carry out inelastic neutron scattering (INS) study of a multifunctional zeolite catalyst (TaAlS-1: Ta-doped MFI zeolite) for the highly selective conversion of methanol to propene. The proposed study will investigate the vibrational spectroscopy (e.g., C-H and O-H stretching modes) of the catalyst, adsorption of guest molecules (methanol and dimethyl ether) and any possible reaction intermediates (e.g., alkenes) on catalyst surface. In particular, this study aims to reveal the roles of Ta(V) sites and Si-O(H)-Al groups in the binding to guest molecules and in the catalytic reactions. This recently-discovered multifunctional catalyst (unpublished) exhibit record high selectivity of propene and propene/ethene ratio for methanol conversion.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB2010255-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/109983314
Provenance
Creator Dr Jiangnan Li; Dr Longfei LIN; Professor Sihai Yang; Dr Svemir Rudic; Dr Hamish Cavaye; Dr Qingqing Mei; Dr Bing An
Publisher ISIS Neutron and Muon Source
Publication Year 2023
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2020-03-12T08:30:00Z
Temporal Coverage End 2020-03-18T08:30:00Z