Magnetic properties of quadruple perovskites containing A- and B-site iron cations

DOI

New quadruple perovskites with nominal compositions LnFe4Ti3O12 (Ln = La, Nd) have recently been discovered through high pressure synthesis. Mössbauer spectra show that these materials are AA'3B4O12 materials where the square planar A' sites are occupied by Fe2+ cations while 25% of the octahedral B sites are occupied by Fe3+. Magnetisation data show a transition near 300 K for both materials; also a 10 K transition for Ln = La, and 50 and 12 K anomalies for Ln = Nd. We propose to collect variable temperature (4 - 300 K) neutron powder diffraction from LaFe4Ti3O12 and NdFe4Ti3O12. The POLARIS or GEM diffractometers are suitable for the study of these small samples (0.3 g) resulting from high-pressure synthesis.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920030-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/105598921
Provenance
Creator Dr Masato Goto; Dr Yuichi Shimakawa; Dr Fabio Denis Romero; Dr Midori Amano; Professor Paul Attfield; Mr Zhenhong Tan; Dr PAULA KAYSER; Dr Ron Smith
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2019-09-18T07:30:00Z
Temporal Coverage End 2019-09-20T13:58:15Z