Understanding quantum and classical proton transfer mechanisms in protic ionic liquid ethylammonium nitrate

DOI

Considerable research efforts have been devoted to polymer electrolyte membranes fuel cells. It has been recently proposed as a promising approach to replace aqueous electrolytes with protic ionic liquids (PILs). The key property of these systems, setting them apart from conventional ionic liquids, is their proton conductivity. A more thorough understanding of proton transfer mechanisms in PILs, including the determination of a relationship between local microscopic dynamics and macroscopic transport properties, is thus crucial to facilitate the design of applications. The aim of this application is to characterize the local proton transfer mechanism both in the classical and in the quantum frame in the prototype PIL ethylammonium nitrate by means of two complementary neutron scattering techniques, i.e Quasi Elastic Neutron Scattering (QENS) and Deep Inelastic Neutron Scattering (DINS).

Identifier
DOI https://doi.org/10.5286/ISIS.E.61004375
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/61004375
Provenance
Creator Dr Sanghamitra Mukhopadhyay; Mrs Isabel Vazquez Fernandez; Dr Maria Grazia Izzo; Professor Ken Seddon; Dr Natalia Plechkova
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2015-06-08T08:00:00Z
Temporal Coverage End 2015-06-15T12:39:05Z