The relative importance of methylation and demethylation in rice paddy soil varies depending on the presence of rice plants

DOI

This data was collected in order to understand the influence of rice plants on methylation and demethylation on methylmercury (MeHg) concentration in rice paddy soil, and to assess which process was more dominant in paddy soil. Soil for the experimental work was collected from the Yolo Bypass, near Sacramento, California, an area with a strong commercial rice growing industry. Experimental work was carried out in growth chambers at the University of Washington. Soil was collected in October 2017 and experimental work was carried out in late 2018-early 2019. We established rice paddy microcosms with and without rice plants (n=6 in each treatment) and maintained them until the planted boxes had reached the peak of vegetative growth. At this time, we amended the soil with stable isotope tracers to measure methylation and demethylation potential rates based on an 8 hour incubation period. From these soil samples, we collected information on soil background (ambient) MeHg, inorganic Hg, total sulfur content, and methylation and demethylation potential rate constants. Information on rice root exudation rates was also collected in an experiment performed in 2019. In brief, the following methods were used for each analysis. Methylmercury concentrations (both ambient and tracer) were measured using using isotope dilution-gas chromatography-ICPMS (Hintelmann et al., 2000). Ambient and tracer THg concentrations were analyzed using isotope dilution-cold vapour-ICPMS. Inorganic Hg was calculated as total Hg minus MeHg. Total sulfur was assessed using EPA-3050 combined with EPA 200.7 on a Thermo-Scientific 6300 ICP spectrometer. Methylation and demethylation potential rate constants were measured using stable isotope tracer and the isotope-dilution method of Hintelmann et al 2000. Rice root exudates were measured from soil-grown plants using the calcium sulfate incubation method of Aulakh et al. (2001).

Identifier
DOI https://doi.org/10.1594/PANGAEA.937557
Related Identifier References https://doi.org/10.1055/s-2001-12905
Related Identifier References https://doi.org/10.1002/etc.5620190909
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.937557
Provenance
Creator Strickman, Rachel J ORCID logo; Larson, Sarah; Haiyong, Huang; Kakouros, Evangelos; Marvin-DiPasquale, Mark M D; Mitchell, Carl P J ORCID logo; Neumann, Rebecca B ORCID logo
Publisher PANGAEA
Publication Year 2021
Funding Reference National Science Foundation https://doi.org/10.13039/100000001 Crossref Funder ID 1740839 https://www.nsf.gov/awardsearch/showAward?AWD_ID=1740839 NSF EAR 1740839
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format application/vnd.openxmlformats-officedocument.spreadsheetml.sheet
Size 60.4 kBytes
Discipline Earth System Research
Spatial Coverage (-122.289 LON, 47.657 LAT)
Temporal Coverage Begin 2018-11-06T00:00:00Z
Temporal Coverage End 2019-01-20T00:00:00Z