QENS Study of Proton Diffusion in Metal-Organic Framework Materials

DOI

The development of new functional metal-organic frameworks (MOFs) as complex proton conductor is receiving increasing attention worldwide. We aim to develop new solid proton conductors based upon MOFs and request 6 days on IRIS to study the motion of active protons in two functional porous MOF materials [MFM-505(La) and MFM-505(Ce)] as a function of temperature. This proposed study will investigate the diffusion properties exhibited by these active protons from the MOF hosts. These two MOFs exhibit high proton conductivity (4.6 x 10-3 S cm-1 at 60 oC under 98%RH). The proposed study aims to reveal the full nature of the proton conductivity by analysing the QENS data together with our MD modelling studies.

Identifier
DOI https://doi.org/10.5286/ISIS.E.84764508
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/84764508
Provenance
Creator Mr Guanhai Cao; Mr Matthew Hill; Dr Victoria Garcia Sakai; Mr Thien Duong Duc; Miss Simona Pili; Dr Christopher Marsh; Professor Martin Schroder; Dr Lei Li; Dr Ian Silverwood; Professor Sihai Yang; Mr Harry Godfrey; Mr Pete Rought; Dr Mark Johnson; Dr Will Trenholme; Miss Anastasiia Cheplakova
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2017-02-19T09:00:00Z
Temporal Coverage End 2017-02-23T09:00:00Z