Probing the [FeFe]-hydrogenase subsite using muon spectroscopy

DOI

Previous ALC measurements of the Fe2(pdt)(CO)4(PMe3)2 and [Fe2(pdt)(CO)4(CN)2]2- (referred to as 1 and 2) model hydrogenase subsites have yielded some intriguing results (RB 1510387). The presence of multiple ligand types at the metal centres of 1 and 2 makes a full analysis of of the muoniation sites complex. We propose a study of a simpler system, the Fe2(pdt)(CO)6, where there is a single ligand type and therefore fewer possible muoniated isomers.

Identifier
DOI https://doi.org/10.5286/ISIS.E.67770843
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/67770843
Provenance
Creator Dr Joseph Wright; Dr Jamie Peck; Dr Upali Jayasooriya; Dr Stephen Cottrell; Professor C J Pickett
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-12-13T09:00:00Z
Temporal Coverage End 2015-12-17T09:00:00Z