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Understanding Amphiphilic Self-Assembly in and by Protic Ionic Liquids
The goal of this project is to understand the intermolecular forces that promote amphiphile self assembly in ethylammonium nitrate (EAN), a room temperature ionic liquid (IL).... -
Structure of Petroleum Asphaltenes in Solution
Asphaltenes are the heaviest end of crude oil and are responsible for a multitude of engineering challenges. They can precipitate from the oil, depositing, blocking pipelines... -
Study of Deep Eutectic Solvents dilutions: nanometer size domains and molecul...
Carbon materials with nanopore structures are of great importance for development of energy storage and gas adsorption devices. The critical parameter is pore size and it is... -
Cononsolvency of Poly(N,N-Diethyl Acrylamide) (PDEA) in water/ethanol mixture...
Cononsolvency is a rare phenomenon that the solubility of a polymer decreases or even vanishes in the mixture of good solvents [Macromolecules 1991, 24, 948]. Although PDEA is... -
The structural role of hydrogen and other guest atoms in graphitic carbon nit...
Carbon nitrides are emerging as an important class of materials with applications that range from Li+ ion and electronic charge storage in batteries and supercapacitors,... -
Effects of Chiral Components on the Structure of Deep Eutectic Solvents
Deep eutectic solvents (DES) are novel liquids composed of inexpensive components, and are non-flammable, with a low volatility. One problem with DES is frequently their... -
Rod-to-Sphere Transition in SDS Micelles in Choline Choride:Urea Deep Eutecti...
Our recent work demonstrates that the details of solvent structure around micelles are accessible using Empirical Potential Structure Refinement methods combined with neutron... -
Investigation of Graphitic Carbon Nitride (g-C3N4) structure
Production of hydrogen from water via visible light driven photocatalytic water splitting is a future technology that may offer important routes to clean fuels. Graphitic carbon... -
Local and long-range solute and solvent ordering in concentrated nanotube gel...
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Solution structure of polyaromatic hydrocarbons
This dataset has no description
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Multiscale time-resolving study of solid state crystallisation from the mesom...
We will exploit the unique capability of Nimrod in the study of the long standing issue of polymer crystallisation. We focus on isotactic polypropylene which has been quenched... -
Reversible B-H Bond Activation at Cationic Rh(III) Centres: Structural Charac...
Catalytic processes leading to the functionalization of organic molecules by boron-containing reagents are highly topical ¿ ranging from transition metal catalysed hydro- and... -
Protein-Ionic liquid interactions: A window into future sustainable processin...
Processing of complex biopolymers, particularly proteins such as keratin and silk, has been hindered by the extremely low solubility and thus accessibility to the protein... -
Ion Binding in Tetradecyltrimethylammonium Surfactant Micelle Solutions
This proposal continues our studies of surfactant micelles using NIMROD, to obtain previously inaccessible details of headgroup-ion interactions. In our previous experiments... -
The Novel Quenching and Partitioning (Q&P) Heat-treatment Process
Q&P heat-treatments typically consist of an ¿Austenitisation - Interrupted Quench ¿ Partition ¿ Final Quench¿ heat treatment process. During the partitioning stage carbon... -
Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41
In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction... -
Role of DMSO in Ionic Liquid / DMSO Mixtures
This proposal aims to study the interactions within a prototypical ionic liquid / co-solvent system. Such systems are currently under investigation as potential solvating media... -
Alcohols in Cationic Surfactant Micelle Solutions
This proposal continues our studies of water and small molecule binding around surfactant micelles using NIMROD, to obtain previously inaccessible details of their molecular... -
Local and long-range ordering in concentrated nanotube solutions
Manipulating nanoparticles in liquids is crucial for their scalable implementation in future technologies. For example, such liquids can be used like paint to create uniform... -
Role of DMSO in Ionic Liquid / DMSO Mixtures
This proposal aims to study the interactions within a prototypical ionic liquid / co-solvent system. Such systems are currently under investigation as potential solvating media...