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The Monolayer Structure of Polyaromatic Hydrocarbons on Graphite
Self-assembled monolayers are employed in the fabrication of organic transistors and organic- electronic devices. Polycyclic aromatic hydrocarbons (PAHs), a class of organic... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
Correlating Structural and Magnetic Disorder in Sc-substituted SCGO (SrCr9Ga3...
A prototypical frustrated magnet in which structural disorder plays a key role is SrCr9pGa12−9pO19 (SCGO). It is postulated that structurally ordered SCGO hosts a... -
Atomic and pore structure of crystallizing zeolite precursors
We will investigate a series of aluminosilicate systems, zeolite chabazite, ZSM-5, Zeolite Y and Zeoltie A and determine the short and medium range order structures and the... -
Structural phase diagram of hydrated silks
The formation of silk fibres in both spiders and silkworms is characterized by a conversion of short range ordered structures in solution into long range ordered beta-sheet rich... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Reorientational dynamics in a low-dimensional glass
Most of the features exhibited by canonical glass-formers can also be found in systems with a high-degree of translational order. In addition to the well-known orientationally... -
Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One... -
Suppression of thermal conductivity in nanostructured ZnO
Thermoelectricity offers solutions for the low-carbon economy through the development of energy-efficient technology. Modest improvement in thermoelectric performance would... -
The pressure dependence of the decomposition temperature of methane hydrate i...
The properties of methane ammonia water mixtures are crucial for models of how the outer planets evolved and yet have not been much studied. This proposal is for beamtime to... -
Deuterated Layered hybrid fluoroperovskites
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Telechelic Polymer - Homopolymer Blends
We have recently embarked on a new 1 year project funded by Michelin to explore the self-associatation and mechanical properties of telechelic rubbery materials. Such materials... -
Crystallization of clathrate hydrates from amorphous THF-water solutions
Understanding clathrate hydrate formation and stability is an urgent issue due to their environmental importance. However, a fundamental understanding of the molecular processes... -
Fate of silver nanoparticles in enhanced wastewater treatment
Building on the success of our earlier work, we now propose to use SANS to examine the floc structure and sedimentation behaviour of silver nanoparticles in wastewater matrices... -
SANS studies of mixed phospholipid:sterol vesicles and their interaction with...
The increasing incidence of pathogenic fungi resistant to treatment with amphotericin B (AmB) has created a demand for novel anti-fungal agents that can circumvent the... -
Determination of the H-H bond lenght of H2/CuBTC MOF (SANDALS)
The rotational line of hydrogen is very clearly measured with TOSCA. For the past few years I have noticed that the changes in the position of the rotational line do not follow... -
Cooling
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Protein-Ionic liquid interactions: A window into future sustainable processin...
Processing of complex biopolymers, particularly proteins such as keratin and silk, has been hindered by the extremely low solubility and thus accessibility to the protein... -
Solid state processing of conjugated polymer-fullerene blends
Blends of fullerenes with conjugated polymers (CP), such as PCBM-P3HT blends, are being extensively investigated for polymer photovoltaic applications. We have been studying the... -
The quest for attractive divalent sulfur - oxygen interactions
Weak nonbonded interactions between a divalent sulfur and an oxygen atom have attracted growing interest because of their roles in determining the structure and the biological...