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SANS DETERMINATION OF CO2 ABSORPTION INTO SURFACTANT STABILISING LAYERS
Recent SAXS measurements have indicated that CO2 can dramatically swell the surfactant layer in w/o microemulsions formed in CO2-swollen oils and also enhance solubilisation... -
Mixed surfactants for positive synergism in dense CO2
This proposal aims to explore a cheaper and more environmental-benign surfactant system for yielding efficient water/CO2 microemulsions. The new surfactants permit high... -
Solvent-induced curvature of micelles
The purpose is to follow a structural evolution as water soluble (normal curvature) micelles are gradually transformed into oil soluble (reversed curvature) aggregates. Although... -
Aggregation of chiral catalysts based on the Trost ligand
The project represents a new application of SANS to investigate chemically sophisticated chiral catalysts, addressing important questions in modern synthetic and catalytic... -
Magnetic ionic liquid surfactants
This proposal is to explore the magnetic properties and molecular dynamics of a new class of magnetic ionic liquid surfactants1 (MILSs) (see Fig. 1). The MILSs investigated here... -
Mixed micelles with "green" surfactants
This proposal aims to explore aqueous phase structures and compositions of a series of mixed surfactants. Although standard surfactant mixtures have been extensively studied... -
Concentrated emulsions as proxy CO2 thickeners
The proposal aims to explore the oil-in-water (brine) high internal phase emulsion systems (HIPEs) formed by nonylphenol ethoxylate surfactants using contrast variation SANS... -
Mixing CO2-philc surfactants and hydrotropes as a new approach to control vis...
One application where liquid CO2 has found success is enhanced oil recovery (CO2-EOR) of crude oil from porous rocks. However, a significant disadvantage of using CO2 in EOR is... -
Surfactant ionic liquids as tuneable structured media
This proposal aims to explore aqueous phase structures of a new range of ionic liquid surfactants (IL-surfs). These IL-surfs have interesting potential applications as reaction... -
Nonfluorous Cosurfactant/Hyperbranched Surfactant Mixtures for W/CO2 Microemu...
This proposal aims to explore cheap and environmental-benign cosurfactants (or cosolvents) for yielding CO2-philic hydrocarbon surfactant/water/CO2 microemulsions (W/CO2... -
Solventless protein liquids: a novel form of biological matter
Solventless protein liquids (SPLS) represent a novel form of biological matter. Recently we reported on the preparation and properties of a solvent-free liquid protein based on... -
Mixed micelles with green surfactants
This proposal aims to explore aqueous phase structures and compositions of a series of mixed surfactants. Although standard petrochemically-derived surfactant mixtures have been... -
Dispersed lamellar phases in dense CO2
This proposal aims to explore these dispersed lamellar phases with a variety of F7H4 derivatives,to help understand their formation in supercritical CO2 (sc-CO2). The focus is... -
Mixed surfactants for dialable organogels
The idea is to be able to ¿dial-up¿ the length and properties of CO2-philic and organo-philic rod-like micelles. This proposal aims to explore mixed surfactant systems in... -
A structural evolution: hydrotrope-alkyl hydrotrope-surfactant
The aim of the proposal is to improve understanding about combinations of normal surfactants and hydrotropes. The systems of study are reference oil-water interfaces, provided... -
Bi-disperse colloids: silica and microemulsions
Surprisingly little work has been done to gain understanding about the nature, stability and properties of nanoparticles dispersed in organic solvents (organosols). Recently... -
Micellar modifiers for CO2
This proposal focuses on a new approach to the formation of rod-like micelles in supercritical CO2 (scCO2). Recent successful high-pressure SANS (HP-SANS) results have shown for... -
Is there a CMC for surfactants in non-aqueous solvents?
The aim of this project is to use SANS to determine if a critical micelle concentration (CMC) exists for the formation of inverse micelles in non-polar solvents. The CMC is a... -
Studies of the mechanism of hydrotropy
The objective is to refine current understanding about the mechanism of hydrotropy with respect to polarity and electrostatic character of hydrotropes and hydrophobic solutes... -
Gold-loaded microgels
Recent results show that gold nanoparticles (Au-NPs) can be included into microgels (MGs). UV-visible spectra (Figure 1) suggest the original Au-NP sols retain their size and...