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SANS DETERMINATION OF CO2 ABSORPTION INTO SURFACTANT STABILISING LAYERS
Recent SAXS measurements have indicated that CO2 can dramatically swell the surfactant layer in w/o microemulsions formed in CO2-swollen oils and also enhance solubilisation... -
Inelastic neutron scattering from H_2 in binary clathrate hydrates
The proposing team is interested in exploring the rotational and translational dynamics of molecular hydrogen trapped in water-based cages (clathrate hydrates). These systems... -
Aggregation of chiral catalysts based on the Trost ligand
The project represents a new application of SANS to investigate chemically sophisticated chiral catalysts, addressing important questions in modern synthetic and catalytic... -
Temperature Effects and Kinetics of Thiolipid Adsorption to Gold Surfaces
We have a programme investigating the structure and function of protein scaffolds oriented on gold surfaces using sulfur chemistry for attachment. The aim is to direct the... -
Nanostructure definition in electrospun fibres of polymer blends
This proposal is part of a research programme which is focused on nano-fibres prepared by electrospinning. The programme is centered on the spinning... -
The impact of synthetic perfumes on surfactant self-assembly.
This proposal is part of a broad collaboration between Oxford, CCLRC, and Unilever in the study of surfactants and mixed surfactants at interfaces and in solution. This is an... -
Search for structural modulation lifting the orbital degeneracy in triangular...
This proposal is part of our research programme on spin and orbital order in frustrated systems. AgNiO2 has a layered crystal structure with Jahn-Teller active Ni3+ ions forming... -
Magnetic order in the triangular quantum magnet AgNiO2
This proposal is part of our research programme on spin and orbital order in frustrated systems. AgNiO2 has a layered crystal structure with Jahn-Teller active Ni3+ ions forming... -
Dynamics within the Plastic Crystal Phases of Hydrogen Chloride
Hydrogen chloride exhibits a complex phase diagram account made of its simple molecular structure. Three crystalline phases are known to exist at ambient pressure below its... -
Mixed micelles with "green" surfactants
This proposal aims to explore aqueous phase structures and compositions of a series of mixed surfactants. Although standard surfactant mixtures have been extensively studied... -
Concentrated emulsions as proxy CO2 thickeners
The proposal aims to explore the oil-in-water (brine) high internal phase emulsion systems (HIPEs) formed by nonylphenol ethoxylate surfactants using contrast variation SANS... -
In situ diffraction studies of the archetypal network glass, SiO2 at high pre...
Silica glass is one of the most widely studies amorphous materials. It is the archetypal glass former, comprising a network of corner-shared SiO4 tetrahedra. Recently a lot of... -
Development of internal strains during compression of Al-Si alloy Al-7Si-0.4Mg
This proposal follows on from our successful experiment on ENGIN-X lin 2006, where we measured the development of strains in the aluminium and silicon phases of a common casting... -
Micelle curvature effects on polyelectrolyte-surfactant film structures
This proposal continues our investigations into polyelectrolyte-surfactant thin films which form at the air-solution interface. Our previous work investigated structure... -
Structural study of oxygen ion conduction in microporous Mayenite
The crystal unit cell of mayenite, 12CaO.7Al2O3, consists of a cubic lattice of [Ca24Al28O64]4+ with the remaining 2*O2- contained in cages, which are linked by channels within... -
Stochastic vs. Intermolecular Motions in Strongly Associated Liquids: The Cas...
Neutron scattering is a powerful technique to study stochastic motions in liquids but it requires an energy resolution well below the meV range. As a consequence, quasielastic... -
Solventless protein liquids: a novel form of biological matter
Solventless protein liquids (SPLS) represent a novel form of biological matter. Recently we reported on the preparation and properties of a solvent-free liquid protein based on... -
Curvature effects in polyelectrolyte-surfactant solution interactions
This proposal continues our investigations into polyelectrolyte-surfactant solutions which form thin films at the air-solution interface. Our previous work has investigated the... -
Dispersed lamellar phases in dense CO2
This proposal aims to explore these dispersed lamellar phases with a variety of F7H4 derivatives,to help understand their formation in supercritical CO2 (sc-CO2). The focus is... -
The XY pyrochlore AFM:spin dynamics upon rare-earth dilution in Er2Ti2O7 (CON...
Er2Ti2O7 constitutes an experimental realization of the <111> easy-plane pyrochlore AFM and orders at 1.1 K into the theoretically predicted spin structure. However, the...