Kinetic studies of the Trost ligand particpating in a catalytic cycle

DOI

The aim is use time-resolved SANS to monitor the changes in aggregation structure of the Trost ligand[1] Pd-catalyst [(DACH-phenyl-TSL)Pd+(η3-C6H9)]BArF- 1 (Figure 1 left) in situ whilst it is participating in a catalytic reaction cycle. The experiments will help to reveal further important details of Pd-Trost ligand oligomer structure for (1)n whilst participating in a catalytic cycle. This will provide valuable information for taming this system so that its power can be reliably and reproducibly harnessed for synthesis.

Identifier
DOI https://doi.org/10.5286/ISIS.E.42588524
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/42588524
Provenance
Creator Dr Gregory Smith; Mr David Yan; Miss Jocelyn Peach; Dr Craig James; Professor Julian Eastoe; Mr Tomas Racys
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2013-10-30T00:00:00Z
Temporal Coverage End 2013-12-04T17:31:50Z