Mechanism of hydride-ion mobility in a novel oxide-hydride

DOI

This proposal requests 7 days of beamtime on the quasielastic neutron scattering spectrometer OSIRIS to investigate the mechanism of hydride ion mobility in the recently discovered LaxSr4-xNiRuO4H4 (x = 0.5, 1, and 1.5) oxide-hydride phases. Ionic conductivity lays at the heart of the function of many technological devices, such as batteries and fuel cells, to name a few. Thus, besides being of considerable fundamental interests, these new materials are as well of technological relevances. The specific aims are to determine the time-scale and geometry of hydride ion dynamics, how it depends on temperature and on composition (x), relate to the dynamical nature of hydride ions in other oxide-hydride phases, and (with time) develop a generic understanding of H dynamics in oxides, stretching from hydridic to protic species.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920398-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/105600482
Provenance
Creator Mr Rasmus Lavén; Dr Maths Karlsson; Dr Franz Demmel; Professor Michael Hayward
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2019-10-02T07:30:00Z
Temporal Coverage End 2019-10-09T07:38:33Z