In-Situ Quasi-Elastic Neutron Scattering Study of a Gas Loaded Indium-Carboxylate Porous Framework

DOI

We request 8 days on IRIS to study the diffusion of adsorbed H2 gas and C2-hydrocarbons molecules within a gated indium-based porous metal-organic framework (MOF) as a function of gas loading and temperature. The proposed study will enable the nature of the diffusion of the gas molecules to be identified, which is of particular interest owing to the hysteretic H2 and hydrocarbons uptake controlled by a gate molecule that is exhibited by this In-MOF. Furthermore the data obtained from the QENS study will enable the activation energy of the diffusion to be quantified and the geometry of the binding sites to be determined.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24090534
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24090534
Provenance
Creator Professor Bill David; Dr Anibal Ramirez-Cuesta; Dr Sam Callear; Professor Martin Schroder; Professor Sihai Yang; Miss Ruth Newby; Mr Chris Morris; Dr Mathew Savage
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2013-05-14T15:14:20Z
Temporal Coverage End 2013-05-29T07:37:36Z